U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on CeF4 by Materials Project
Abstract
CeF4 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. there are two inequivalent Ce4+ sites. In the first Ce4+ site, Ce4+ is bonded in a 8-coordinate geometry to eight F1- atoms. There are a spread of Ce–F bond distances ranging from 2.23–2.33 Å. In the second Ce4+ site, Ce4+ is bonded in a 8-coordinate geometry to eight F1- atoms. There are six shorter (2.26 Å) and two longer (2.37 Å) Ce–F bond lengths. There are seven inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted bent 150 degrees geometry to two equivalent Ce4+ atoms. In the second F1- site, F1- is bonded in a distorted linear geometry to two equivalent Ce4+ atoms. In the third F1- site, F1- is bonded in a linear geometry to two Ce4+ atoms. In the fourth F1- site, F1- is bonded in a bent 150 degrees geometry to two Ce4+ atoms. In the fifth F1- site, F1- is bonded in a linear geometry to two equivalent Ce4+ atoms. In the sixth F1- site, F1- is bonded in a distorted bent 150 degrees geometry to two Ce4+ atoms. In the seventh F1- site, F1- is bonded in amore »
- Authors:
- Publication Date:
- Other Number(s):
- mp-542001
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; CeF4; Ce-F
- OSTI Identifier:
- 1266352
- DOI:
- https://doi.org/10.17188/1266352
Citation Formats
The Materials Project. Materials Data on CeF4 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1266352.
The Materials Project. Materials Data on CeF4 by Materials Project. United States. doi:https://doi.org/10.17188/1266352
The Materials Project. 2020.
"Materials Data on CeF4 by Materials Project". United States. doi:https://doi.org/10.17188/1266352. https://www.osti.gov/servlets/purl/1266352. Pub date:Sat Jul 18 00:00:00 EDT 2020
@article{osti_1266352,
title = {Materials Data on CeF4 by Materials Project},
author = {The Materials Project},
abstractNote = {CeF4 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. there are two inequivalent Ce4+ sites. In the first Ce4+ site, Ce4+ is bonded in a 8-coordinate geometry to eight F1- atoms. There are a spread of Ce–F bond distances ranging from 2.23–2.33 Å. In the second Ce4+ site, Ce4+ is bonded in a 8-coordinate geometry to eight F1- atoms. There are six shorter (2.26 Å) and two longer (2.37 Å) Ce–F bond lengths. There are seven inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted bent 150 degrees geometry to two equivalent Ce4+ atoms. In the second F1- site, F1- is bonded in a distorted linear geometry to two equivalent Ce4+ atoms. In the third F1- site, F1- is bonded in a linear geometry to two Ce4+ atoms. In the fourth F1- site, F1- is bonded in a bent 150 degrees geometry to two Ce4+ atoms. In the fifth F1- site, F1- is bonded in a linear geometry to two equivalent Ce4+ atoms. In the sixth F1- site, F1- is bonded in a distorted bent 150 degrees geometry to two Ce4+ atoms. In the seventh F1- site, F1- is bonded in a distorted linear geometry to two Ce4+ atoms.},
doi = {10.17188/1266352},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sat Jul 18 00:00:00 EDT 2020},
month = {Sat Jul 18 00:00:00 EDT 2020}
}