Materials Data on LiBiO2 by Materials Project
Abstract
LiBiO2 crystallizes in the orthorhombic Ibam space group. The structure is two-dimensional and consists of two LiBiO2 sheets oriented in the (0, 0, 1) direction. Li1+ is bonded to four equivalent O2- atoms to form a mixture of distorted edge and corner-sharing LiO4 tetrahedra. All Li–O bond lengths are 2.00 Å. Bi3+ is bonded in a distorted rectangular see-saw-like geometry to four O2- atoms. There are a spread of Bi–O bond distances ranging from 2.08–2.42 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted T-shaped geometry to three equivalent Bi3+ atoms. In the second O2- site, O2- is bonded in a 5-coordinate geometry to four equivalent Li1+ and one Bi3+ atom.
- Authors:
- Publication Date:
- Other Number(s):
- mp-28253
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; LiBiO2; Bi-Li-O
- OSTI Identifier:
- 1202383
- DOI:
- https://doi.org/10.17188/1202383
Citation Formats
The Materials Project. Materials Data on LiBiO2 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1202383.
The Materials Project. Materials Data on LiBiO2 by Materials Project. United States. doi:https://doi.org/10.17188/1202383
The Materials Project. 2020.
"Materials Data on LiBiO2 by Materials Project". United States. doi:https://doi.org/10.17188/1202383. https://www.osti.gov/servlets/purl/1202383. Pub date:Wed Jul 15 00:00:00 EDT 2020
@article{osti_1202383,
title = {Materials Data on LiBiO2 by Materials Project},
author = {The Materials Project},
abstractNote = {LiBiO2 crystallizes in the orthorhombic Ibam space group. The structure is two-dimensional and consists of two LiBiO2 sheets oriented in the (0, 0, 1) direction. Li1+ is bonded to four equivalent O2- atoms to form a mixture of distorted edge and corner-sharing LiO4 tetrahedra. All Li–O bond lengths are 2.00 Å. Bi3+ is bonded in a distorted rectangular see-saw-like geometry to four O2- atoms. There are a spread of Bi–O bond distances ranging from 2.08–2.42 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted T-shaped geometry to three equivalent Bi3+ atoms. In the second O2- site, O2- is bonded in a 5-coordinate geometry to four equivalent Li1+ and one Bi3+ atom.},
doi = {10.17188/1202383},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Wed Jul 15 00:00:00 EDT 2020},
month = {Wed Jul 15 00:00:00 EDT 2020}
}
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