U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on SbBrF8 by Materials Project
Abstract
SbBrF8 crystallizes in the orthorhombic Pcca space group. The structure is one-dimensional and consists of two SbBrF8 ribbons oriented in the (0, 1, 0) direction. Sb3+ is bonded in an octahedral geometry to six F1- atoms. There is four shorter (1.90 Å) and two longer (1.99 Å) Sb–F bond length. Br5+ is bonded in a square co-planar geometry to four F1- atoms. There are two shorter (1.77 Å) and two longer (2.25 Å) Br–F bond lengths. There are four inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the third F1- site, F1- is bonded in a distorted bent 150 degrees geometry to one Sb3+ and one Br5+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to one Br5+ atom.
- Authors:
- Publication Date:
- Other Number(s):
- mp-27308
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; SbBrF8; Br-F-Sb
- OSTI Identifier:
- 1201517
- DOI:
- https://doi.org/10.17188/1201517
Citation Formats
The Materials Project. Materials Data on SbBrF8 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1201517.
The Materials Project. Materials Data on SbBrF8 by Materials Project. United States. doi:https://doi.org/10.17188/1201517
The Materials Project. 2020.
"Materials Data on SbBrF8 by Materials Project". United States. doi:https://doi.org/10.17188/1201517. https://www.osti.gov/servlets/purl/1201517. Pub date:Wed Apr 29 00:00:00 EDT 2020
@article{osti_1201517,
title = {Materials Data on SbBrF8 by Materials Project},
author = {The Materials Project},
abstractNote = {SbBrF8 crystallizes in the orthorhombic Pcca space group. The structure is one-dimensional and consists of two SbBrF8 ribbons oriented in the (0, 1, 0) direction. Sb3+ is bonded in an octahedral geometry to six F1- atoms. There is four shorter (1.90 Å) and two longer (1.99 Å) Sb–F bond length. Br5+ is bonded in a square co-planar geometry to four F1- atoms. There are two shorter (1.77 Å) and two longer (2.25 Å) Br–F bond lengths. There are four inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the third F1- site, F1- is bonded in a distorted bent 150 degrees geometry to one Sb3+ and one Br5+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to one Br5+ atom.},
doi = {10.17188/1201517},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Wed Apr 29 00:00:00 EDT 2020},
month = {Wed Apr 29 00:00:00 EDT 2020}
}