Materials Data on FePb2(CN)6 by Materials Project

doi:10.17188/1196512

Title: Materials Data on FePb2(CN)6 by Materials Project

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Abstract

Pb2Fe(CN)6 crystallizes in the trigonal P-3 space group. The structure is two-dimensional and consists of one iron molecule and one Pb(CN)3 sheet oriented in the (0, 0, 1) direction. In the Pb(CN)3 sheet, Pb2+ is bonded to six equivalent N3- atoms to form distorted edge-sharing PbN6 octahedra. There are three shorter (2.47 Å) and three longer (2.88 Å) Pb–N bond lengths. C+1.83+ is bonded in a distorted single-bond geometry to one N3- atom. The C–N bond length is 1.18 Å. N3- is bonded in a distorted single-bond geometry to two equivalent Pb2+ and one C+1.83+ atom.

Authors:: The Materials Project

Publication Date:: Fri Jul 17 00:00:00 EDT 2020

Other Number(s):: mp-21239

DOE Contract Number:: AC02-05CH11231; EDCBEE

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Collaborations:: MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE

Keywords:: crystal structure; FePb2(CN)6; C-Fe-N-Pb

OSTI Identifier:: 1196512

DOI:: https://doi.org/10.17188/1196512

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                    The Materials Project. Materials Data on FePb2(CN)6 by Materials Project.  United States: N. p., 2020. 
        Web.  doi:10.17188/1196512.

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                    The Materials Project. Materials Data on FePb2(CN)6 by Materials Project.  United States.  doi:https://doi.org/10.17188/1196512

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                    The Materials Project. 2020.  
"Materials Data on FePb2(CN)6 by Materials Project".  United States.  doi:https://doi.org/10.17188/1196512.  https://www.osti.gov/servlets/purl/1196512. Pub date:Fri Jul 17 00:00:00 EDT 2020

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@article{osti_1196512,

  title        = {Materials Data on FePb2(CN)6 by Materials Project},

  author       = {The Materials Project},

  abstractNote = {Pb2Fe(CN)6 crystallizes in the trigonal P-3 space group. The structure is two-dimensional and consists of one iron molecule and one Pb(CN)3 sheet oriented in the (0, 0, 1) direction. In the Pb(CN)3 sheet, Pb2+ is bonded to six equivalent N3- atoms to form distorted edge-sharing PbN6 octahedra. There are three shorter (2.47 Å) and three longer (2.88 Å) Pb–N bond lengths. C+1.83+ is bonded in a distorted single-bond geometry to one N3- atom. The C–N bond length is 1.18 Å. N3- is bonded in a distorted single-bond geometry to two equivalent Pb2+ and one C+1.83+ atom.},

  doi          = {10.17188/1196512},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {Fri Jul 17 00:00:00 EDT 2020},

  month        = {Fri Jul 17 00:00:00 EDT 2020}

}

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DOI: https://doi.org/10.17188/1196512

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