U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Sr2VO4 by Materials Project
Abstract
Sr2VO4 is (La,Ba)CuO4 structured and crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Sr2+ is bonded in a 9-coordinate geometry to nine O2- atoms. There are a spread of Sr–O bond distances ranging from 2.49–2.72 Å. V4+ is bonded to six O2- atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 0°. There is four shorter (1.92 Å) and two longer (2.05 Å) V–O bond length. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted linear geometry to four equivalent Sr2+ and two equivalent V4+ atoms. In the second O2- site, O2- is bonded to five equivalent Sr2+ and one V4+ atom to form a mixture of distorted edge and corner-sharing OSr5V octahedra. The corner-sharing octahedra tilt angles range from 0–6°.
- Authors:
- Publication Date:
- Other Number(s):
- mp-18972
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Sr2VO4; O-Sr-V
- OSTI Identifier:
- 1193747
- DOI:
- https://doi.org/10.17188/1193747
Citation Formats
The Materials Project. Materials Data on Sr2VO4 by Materials Project. United States: N. p., 2018.
Web. doi:10.17188/1193747.
The Materials Project. Materials Data on Sr2VO4 by Materials Project. United States. doi:https://doi.org/10.17188/1193747
The Materials Project. 2018.
"Materials Data on Sr2VO4 by Materials Project". United States. doi:https://doi.org/10.17188/1193747. https://www.osti.gov/servlets/purl/1193747. Pub date:Wed Oct 17 00:00:00 EDT 2018
@article{osti_1193747,
title = {Materials Data on Sr2VO4 by Materials Project},
author = {The Materials Project},
abstractNote = {Sr2VO4 is (La,Ba)CuO4 structured and crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Sr2+ is bonded in a 9-coordinate geometry to nine O2- atoms. There are a spread of Sr–O bond distances ranging from 2.49–2.72 Å. V4+ is bonded to six O2- atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 0°. There is four shorter (1.92 Å) and two longer (2.05 Å) V–O bond length. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted linear geometry to four equivalent Sr2+ and two equivalent V4+ atoms. In the second O2- site, O2- is bonded to five equivalent Sr2+ and one V4+ atom to form a mixture of distorted edge and corner-sharing OSr5V octahedra. The corner-sharing octahedra tilt angles range from 0–6°.},
doi = {10.17188/1193747},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Wed Oct 17 00:00:00 EDT 2018},
month = {Wed Oct 17 00:00:00 EDT 2018}
}