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Title: Effect of Produced HCl during the Catalysis on Micro- and Mesoporous MOFs

Journal Article · · Crystal Growth & Design, 10(9):4118-4122
DOI:https://doi.org/10.1021/cg100796e· OSTI ID:989428

This communication reports the influence of alkylation reaction byproducts, particularly HCl, on MOF-5 with unusual structural transformation to starting precursor and yet maintaining the great catalytic activity in terms of high conversion and selectivity towards the less bulky para-oriented products.

Research Organization:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab. (EMSL)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-76RL01830
OSTI ID:
989428
Report Number(s):
PNNL-SA-70760; XW839C; 35599; KC0201050; TRN: US201019%%432
Journal Information:
Crystal Growth & Design, 10(9):4118-4122, Vol. 10, Issue 9; ISSN 1528-7483
Country of Publication:
United States
Language:
English