Passive Measurement of Hydrogen Ground State Rotational and Vibrational Temperatures in Kinetic Plasmas
A dipole-quadrupole electron-impact excitation model, consistent with molecular symmetry rules, is presented to fit ro-vibronic spectra of the hydrogen Fulcher-α Q-branch line emissions for passively measuring the rotational temperature of hydrogen neutral molecules in kinetic plasmas with the coronal equilibrium approximation. A quasi-rotational temperature and quadrupole contribution factor are adjustable parameters in the model. Quadrupole excitation is possible due to a violation of the 1st Born approximation for low to medium energy electrons (up to several hundred eV). The Born-Oppenheimer and Franck-Condon approximations are implicitly shown to hold. A quadrupole contribution of 10% is shown to fit experimental data at several temperatures from different experiments with electron energies from several to 100 eV. A convenient chart is produced to graphically determine the vibrational temperature of the hydrogen molecules from diagonal band intensities, if the ground state distribution is Boltzmann. Hydrogen vibrational modes are long-lived, surviving up to thousands of wall collisions, consistent with multiple other molecular dynamics computational results. The importance of inter-molecular collisions during a plasma pulse are also discussed.
- Research Organization:
- Princeton Plasma Physics Lab. (PPPL), Princeton, NJ (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC)
- DOE Contract Number:
- DE-AC02-09CH11466
- OSTI ID:
- 988887
- Report Number(s):
- PPPL-4548; TRN: US1007027
- Country of Publication:
- United States
- Language:
- English
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