Nighttime chemical evolution of aerosol and trace gases in a power plant plume: Implications for secondary organic nitrate and organosulfate aerosol formation, NO3 radical chemistry, and N2O5 heterogeneous hydrolysis

Journal Article · Tue Jun 01 04:00:00 EDT 2010 · Journal of Geophysical Research

DOI:https://doi.org/10.1029/2009JD013250· OSTI ID:988796

Zaveri, R A; Kleinman, L; Berkowitz, C M; Brechtel, F J; Gilles, M K; Hubbe, J M; Jayne, J T; Laskin, A; Madronich, S; Onasch, T B; Pekour, M S; Springston, S R; Thornton, J A; Tivanski, A V; Worsnop, D R

Nighttime chemical evolution of aerosol and trace gases in a coal-fired power plant plume was monitored with the Department of Energy Grumman Gulfstream-1 aircraft during the 2002 New England Air Quality Study field campaign. Quasi-Lagrangian sampling in the plume at increasing downwind distances and processing times was guided by a constant-volume balloon that was released near the power plant at sunset. While no evidence of fly ash particles was found, concentrations of particulate organics, sulfate, and nitrate were higher in the plume than in the background air. The enhanced sulfate concentrations were attributed to direct emissions of gaseous H{sub 2}SO{sub 4}, some of which had formed new particles as evidenced by enhanced concentrations of nucleation-mode particles in the plume. The aerosol species were internally mixed and the particles were acidic, suggesting that particulate nitrate was in the form of organic nitrate. The enhanced particulate organic and nitrate masses in the plume were inferred as secondary organic aerosol, which was possibly formed from NO{sub 3} radical-initiated oxidation of isoprene and other trace organic gases in the presence of acidic sulfate particles. Microspectroscopic analysis of particle samples suggested that some sulfate was in the form of organosulfates. Microspectroscopy also revealed the presence of sp{sup 2} hybridized C = C bonds, which decreased with increasing processing time in the plume, possibly because of heterogeneous chemistry on particulate organics. Constrained plume modeling analysis of the aircraft and tetroon observations showed that heterogeneous hydrolysis of N{sub 2}O{sub 5} was negligibly slow. These results have significant implications for several issues related to the impacts of power plant emissions on air quality and climate.

• Research Organization: BROOKHAVEN NATIONAL LABORATORY (BNL)
• Sponsoring Organization: Doe - Office Of Science
• DOE Contract Number: AC02-98CH10886
• OSTI ID: 988796
• Report Number(s): BNL--93893-2010-JA; KP1701000
• Journal Information: Journal of Geophysical Research, Journal Name: Journal of Geophysical Research Journal Issue: d12 Vol. 115; ISSN JGREA2; ISSN 0148-0227
• Country of Publication: United States
• Language: English

Related Subjects

54 ENVIRONMENTAL SCIENCES
AEROSOLS
AIR QUALITY
AIRCRAFT
CHEMISTRY
FLY ASH
GASES
HYDROLYSIS
ISOPRENE
NITRATES
OXIDATION
PARTICULATES
PLUMES
POWER PLANTS
PROCESSING
RADICALS
SAMPLING
SIMULATION
SULFATES