Construction of a Novel Zn₋Ni Trinuclear Schiff Base and a Ni2+ Chemosensor
- South China Normal Univ., Guangzhou (China)
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
The novel Schiff base Zn-Ni trinuclear complex (Zn[Ni(sy- L2)]2(SCN)2, where sy-H2L2 = H2acacen = bis(acetylacetone)ethylenediamine), which is the first trinuclear compound based on symmetric acacen-base Schiff base ligand, was constructed through Ni2+-selective assembly of chemosensor Schiff base zinc compound Zn[(sy-H2L2)(SCN)]2∙(CH3CN)2.
- Research Organization:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC05-76RL01830
- OSTI ID:
- 986687
- Report Number(s):
- PNNL-SA--73793; KC0201050
- Journal Information:
- Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 16 Vol. 49; ISSN 0020-1669
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
Similar Records
Auxiliary Ligand-Dependent Assembly of Several Ni/Ni-Cd Compounds with N 2 O 2 Donor Tetradentate Symmetrical Schiff Base Ligand
Solid chemistry of the Zn{sup II}/1,2,4-triazolate/anion system: Separation of 2D isoreticular layers tuned by the terminal counteranions X (X=Cl{sup -}, Br{sup -}, I{sup -}, SCN{sup -})
Journal Article
·
Wed Nov 03 00:00:00 EDT 2010
· Crystal Growth and Design
·
OSTI ID:1000588
Solid chemistry of the Zn{sup II}/1,2,4-triazolate/anion system: Separation of 2D isoreticular layers tuned by the terminal counteranions X (X=Cl{sup -}, Br{sup -}, I{sup -}, SCN{sup -})
Journal Article
·
Sun Dec 14 23:00:00 EST 2008
· Journal of Solid State Chemistry
·
OSTI ID:21212138