Desulfurization Reactions on Surfaces of Metal Carbides: Photoemission and Density-Functional Studies
High-resolution photoemission and density functional (DF) calculations were used to study the interaction of atomic sulfur and S-containing molecules with metal carbides in which the carbon/metal ratio varies from 0.5 to 1 (M2C and MC, M = Ti, V or Mo). In these compounds, the C sites cannot be considered as simple spectators. They moderate the reactivity of the metal centers and provide bonding sites for adsorbates. For example, the adsorption of S on TiC(001) induces a large positive shift (1.0-1.3 eV) in the C 1s core level. DF calculations give a CTiTi hollow as the most stable site for the S adatoms. There is a correlation between the adsorption energy of S or thiophene and shifts in the centroid of the metal d band induced by metal-carbon bonding in the metal carbides. The M2C and MC carbides have difficulty obeying Sabatier's principle for being good HDS catalysts because some of them interact too strongly with the products (M2C stoichiometry) and the others have problems dissociating the reactants (MC stoichiometry). The addition of small Au nanoparticles is an efficient way for enhancing the HDS activity of MC catalysts. In spite of the very poor desulfurization performance of TiC and MoC, the Au/TiC and Au/MoC systems display an HDS activity comparable or higher than that of conventional Ni/MoS{sub x} catalysts. The Au nanoparticles probably increase the HDS activity of the metal carbides by enhancing the adsorption energy of thiophene and by helping in the dissociation of H2 to produce the hydrogen necessary for the hydrogenolysis of C-S bonds and the removal of sulfur.
- Research Organization:
- Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source
- Sponsoring Organization:
- Doe - Office Of Science
- DOE Contract Number:
- DE-AC02-98CH10886
- OSTI ID:
- 985819
- Report Number(s):
- BNL-90331-2010-JA; R&D Project: CO-009; KC0302010; TRN: US201017%%56
- Journal Information:
- Topics in Catalysis, Vol. 53, Issue 5-6; ISSN 1022-5528
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ADSORPTION
BONDING
CARBIDES
CATALYSTS
DESULFURIZATION
DISSOCIATION
FUNCTIONALS
HYDROGEN
PERFORMANCE
PHOTOEMISSION
REMOVAL
STOICHIOMETRY
SULFUR
THIOPHENE
inorganic
organic
physical and analytical chemistry
national synchrotron light source