A Synthetic High-Spin Oxoiron(IV) Complex: Generation, Spectroscopic Characterization, and Reactivity
Journal Article
·
· Angewandte Chemie. International Edition in English
The high-yield generation of a synthetic high-spin oxoiron(IV) complex, (Fe{sup IV}(O)(TMG{sub 3}tren)){sup 2+} (TMG{sub 3}tren = 1,1,1-tris{l_brace}2-(N2-(1,1,3,3-tetramethylguanidino))ethyl{r_brace}amine), has been achieved by using the very bulky tetradentate TMG{sub 3}tren ligand, in order to both sterically protect the oxoiron(IV) moiety and enforce a trigonal bipyramidal geometry at the iron center, for which an S=2 ground state is favored.
- Research Organization:
- Brookhaven National Laboratory (BNL) National Synchrotron Light Source
- Sponsoring Organization:
- Doe - Office Of Science
- DOE Contract Number:
- AC02-98CH10886
- OSTI ID:
- 979992
- Report Number(s):
- BNL--92910-2010-JA
- Journal Information:
- Angewandte Chemie. International Edition in English, Journal Name: Angewandte Chemie. International Edition in English Journal Issue: 20 Vol. 48; ISSN 0570-0833
- Country of Publication:
- United States
- Language:
- English
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