Base metal dehydrogenation of amine-boranes

Blacquiere, Johanna Marie; Keaton, Richard Jeffrey; Baker, Ralph Thomas

Base metal dehydrogenation of amine-boranes

Patent · Tue Jun 09 00:00:00 EDT 2009

OSTI ID:972292

Blacquiere, Johanna Marie ^[1]; Keaton, Richard Jeffrey ^[2]; Baker, Ralph Thomas ^[3]

Ottawa, CA
Pearland, TX
Los Alamos, NM

A method of dehydrogenating an amine-borane having the formula R.sup.1H.sub.2N--BH.sub.2R.sup.2 using base metal catalyst. The method generates hydrogen and produces at least one of a [R.sup.1HN--BHR.sup.2].sub.m oligomer and a [R.sup.1N--BR.sup.2].sub.n oligomer. The method of dehydrogenating amine-boranes may be used to generate H.sub.2 for portable power sources, such as, but not limited to, fuel cells.

Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM

Sponsoring Organization:: United States Department of Energy

DOE Contract Number:: W-7405-ENG-36; AC52-06NA25396

Assignee:: Los Alamos National Security, LLC (Los Alamos, NM)

Patent Number(s):: 7,544,837

Application Number:: 11/590,136

OSTI ID:: 972292

Country of Publication:: United States

Language:: English

References (5)

A safe, portable, hydrogen gas generator using aqueous borohydride solution and Ru catalyst Amendola, S. International Journal of Hydrogen Energy, Vol. 25, Issue 10 https://doi.org/10.1016/S0360-3199(00)00021-5	journal	October 2000
11B NMR studies of the thermal decomposition of ammoniaborane in solution Wang, J. S.; Geanangel, R. A. Inorganica Chimica Acta, Vol. 148, Issue 2 https://doi.org/10.1016/S0020-1693(00)87499-X	journal	August 1988
Catalytic Dehydrocoupling of Amine-Borane Adducts to form Aminoboranes and Borazines Jaska, Cory A.; Temple, Karen; Lough, Alan J. Phosphorus, Sulfur, and Silicon and the Related Elements, Vol. 179, Issue 4-5 https://doi.org/10.1080/10426500490426683	journal	April 2004
Transition Metal-Catalyzed Formation of Boron−Nitrogen Bonds: Catalytic Dehydrocoupling of Amine-Borane Adducts to Form Aminoboranes and Borazines Jaska, Cory A.; Temple, Karen; Lough, Alan J. Journal of the American Chemical Society, Vol. 125, Issue 31 https://doi.org/10.1021/ja030160l	journal	August 2003
An ultrasafe hydrogen generator: aqueous, alkaline borohydride solutions and Ru catalyst Amendola, Steven C.; Sharp-Goldman, Stefanie L.; Janjua, M. Saleem Journal of Power Sources, Vol. 85, Issue 2 https://doi.org/10.1016/S0378-7753(99)00301-8	journal	February 2000

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