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Vitreous carbon mask substrate for X-ray lithography

Patent ·
OSTI ID:971535
The present invention is directed to the use of vitreous carbon as a substrate material for providing masks for X-ray lithography. The new substrate also enables a small thickness of the mask absorber used to pattern the resist, and this enables improved mask accuracy. An alternative embodiment comprised the use of vitreous carbon as a LIGA substrate wherein the VC wafer blank is etched in a reactive ion plasma after which an X-ray resist is bonded. This surface treatment provides a surface enabling good adhesion of the X-ray photoresist and subsequent nucleation and adhesion of the electrodeposited metal for LIGA mold-making while the VC substrate practically eliminates secondary radiation effects that lead to delamination of the X-ray resist form the substrate, the loss of isolated resist features, and the formation of a resist layer adjacent to the substrate that is insoluble in the developer.
Research Organization:
Sandia National Laboratories (SNL-CA), Livermore, CA
Sponsoring Organization:
United States Department of Energy
DOE Contract Number:
AC04-94AL85000
Assignee:
Sandia Corporation (Livermore, CA)
Patent Number(s):
7,608,367
Application Number:
11/192,797
OSTI ID:
971535
Country of Publication:
United States
Language:
English

References (14)

Ti- and Be-X-ray masks with alignment windows for the LIGA process journal March 1991
Microfabrication of freestanding metal structures using graphite substrate journal January 2003
Fabrication of HARM structures by deep-X-ray lithography using graphite mask technology journal February 2000
Transfer mask for high-aspect-ratio microlithography conference May 1995
Cost-effective masks for deep x-ray lithography conference April 2003
Characterisation of defects in very high deep-etch X-ray lithography microstructures journal February 1998
Adhesion of Ni-structures on Al 2 O 3 ceramic substrates used for the sacrificial layer technique journal April 2000
Alternative resist adhesion and electroplating layers for LIGA process journal August 2000
Adhesion promotion of Cu on C by Cr intermediate layers investigated by the SIMS method journal October 2002
Adhesion problems in deep-etch x-ray lithography caused by fluorescence radiation from the plating base journal January 1994
Microstructuring of glassy carbon: comparison of laser machining and reactive ion etching journal April 2004
Fabrication of graphite masks for deep and ultradeep x-ray lithography conference August 2000
Fabrication of microstructures with high aspect ratios and great structural heights by synchrotron radiation lithography, galvanoforming, and plastic moulding (LIGA process) journal May 1986
Investigation of the adhesive strength of PMMA structures on substrates obtained by deep X-ray lithography journal January 1996

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