Chloride Metathesis and Dimethylamide Transfer in the Reaction of TaCl(NMe2)4 with ZnMe2 and MeMgCl: Spectroscopic Studies and X-ray Diffraction Structures of TaCl(Me)(NMe2)3 and ZnCl2(NHMe2)2
Journal Article
·
· Journal of Chemical Crystallography
- ORNL
- University of North Texas
The reaction of TaCl(NMe2)4 with ZnMe2 in hydrocarbon solvent has been examined and found to give a mixture of TaCl(Me)(NMe2)3, TaMe(NMe2)4, and Ta(NMe2)5 by 1H NMR spectroscopy. Depending upon the work-up conditions employed, the compounds TaCl(Me)(NMe2)3 and ZnCl2(NHMe2)2 have been isolated and structurally characterized by X-ray crystallography. TaCl(NMe2)4 reacts with MeMgCl is a similar fashion and affords TaCl(Me)(NMe2)3 and Ta(NMe2)5 as the principal reaction products.
- Research Organization:
- Oak Ridge National Laboratory (ORNL)
- Sponsoring Organization:
- SC USDOE - Office of Science (SC)
- DOE Contract Number:
- AC05-00OR22725
- OSTI ID:
- 970929
- Journal Information:
- Journal of Chemical Crystallography, Journal Name: Journal of Chemical Crystallography Journal Issue: 2 Vol. 40; ISSN JCCYEV; ISSN 1074-1542
- Country of Publication:
- United States
- Language:
- English
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