New high-nitrogen energetic materials for gas generators in space ordnance
High-nitrogen nitroheterocyclic energetic compounds are used as explosives, propellants, and gas generants when safe, thermally stable, cool-burning energetic materials are desired. A series of compounds are compared for sensitivity properties and calculated burn performance. Thermodynamic equilibrium calculations by NASA/Lewis rocket propellant and Blake gun propellant codes gave flame temperatures, average molecular weight, and identity of the equilibrium burn products for ambient, rocket, and gun pressure environments. These compounds were subjected to calculations both as monopropellants and as 50/50 weight ratio mixtures with ammonium nitrate (AN). Special attention was paid to calculated toxic products such as carbon monoxide and hydrogen cyanide, and how these were affected by the addition of an oxidizer AN. Several compounds were noted for further calculations of a formulation ad experimental evaluation.
- Research Organization:
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- W-7405-ENG-36
- OSTI ID:
- 97041
- Report Number(s):
- LA-UR-95-2384; CONF-950720-9; ON: DE95016821
- Resource Relation:
- Conference: AIAA/SAE/ASME joint propulsion conference and exhibit, San Diego, CA (United States), 10-12 Jul 1995; Other Information: PBD: [1995]
- Country of Publication:
- United States
- Language:
- English
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