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Local Polarization Switching Piezoresponse Force Microscopy

Journal Article · · Ferroelectrics

Piezoresponse Force Spectroscopy (PFS) has emerged as a powerful tool for probing polarization dynamics on the nanoscale. Application of a dc bias to a nanoscale probe in contact with a ferroelectric surface results in the nucleation and growth of a ferroelectric domain below the probe apex. The latter affects local electromechanical response detected by the probe. Resulting hysteresis loop contains information on local ferroelectric switching. The self-consistent analysis of the PFS data requires (a) deriving the thermodynamic parameters of domain nucleation and (b) establishing the relationships between domain parameters and PFM signal. Here, we analyze the early stages of switching processes and the effect of screening on the surface and at the domain wall on local polarization reversal mechanism. It is shown that the screening control both the domain nucleation activation energy and hysteresis loop saturation rate.

Research Organization:
Oak Ridge National Laboratory (ORNL)
Sponsoring Organization:
SC USDOE - Office of Science (SC)
DOE Contract Number:
AC05-00OR22725
OSTI ID:
965289
Journal Information:
Ferroelectrics, Journal Name: Ferroelectrics Journal Issue: 1 Vol. 354
Country of Publication:
United States
Language:
English

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