Syntheses, Spectroscopic Data, and X-ray Diffraction Structures of the Heterometallic RuRe Face-shared Bioctahedral (eta(6)-cymene)Ru(mu-Cl)(3)Re(CO)(3) and MnRu2 Edge-shared Trioctahedral [fac-ClRu(CO)(3)](2)(mu-Cl)(4)Mn(H2O)(2) Complexes
Journal Article
·
· Journal of Chemical Crystallography
- ORNL
- University of North Texas
Thermolysis of the diruthenium compound [(eta(6)-cymene)RuCl2](2) (1) with ClRe(CO)(5) (2) leads to the formation of the new confacial bioctahedral compound (eta(6)-cymene) Ru(mu-Cl)(3)Re(CO)(3) (3) in good yields; the same product has also been isolated when a mixture of 1 and 2 is irradiated with near UV-vis light for an extended period of time. Heating 1 and ClMn(CO)(5) (4) does not furnish the corresponding manganese analogue of 3 but rather the trioctahedral halide-bridged product [fac-ClRu(CO)(3)](2)(mu-Cl)(4)Mn(H2O)(2) (5). 3 and 5 have been fully characterized in solution and their molecular structures established by X-ray crystallography.
- Research Organization:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC)
- DOE Contract Number:
- DE-AC05-00OR22725
- OSTI ID:
- 963409
- Journal Information:
- Journal of Chemical Crystallography, Vol. 39, Issue 8; ISSN 1074-1542
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
MANGANESE COMPLEXES
RUTHENIUM COMPLEXES
RHENIUM COMPLEXES
MOLECULAR STRUCTURE
X-RAY DIFFRACTION
HEAT TREATMENTS
SYNTHESIS
SPECTROSCOPY
Keywords: Ruthenium-rhenium compounds
Manganese-ruthenium compounds
Halide-bridged compounds
Mixed-metal compounds
Crystal structure
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
MANGANESE COMPLEXES
RUTHENIUM COMPLEXES
RHENIUM COMPLEXES
MOLECULAR STRUCTURE
X-RAY DIFFRACTION
HEAT TREATMENTS
SYNTHESIS
SPECTROSCOPY
Keywords: Ruthenium-rhenium compounds
Manganese-ruthenium compounds
Halide-bridged compounds
Mixed-metal compounds
Crystal structure