Indirectly detected through-bond chemical shift correlation NMR spectroscopy in solids under fast MAS: Studies of organic-inorganic hybrid materials
Journal Article
·
· Journal of Magnetic Resonance
OSTI ID:962897
Indirectly detected, through-bond NMR correlation spectra between {sup 13}C and {sup 1}H nuclei are reported for the first time in solid state. The capabilities of the new method are demonstrated using naturally abundant organic-inorganic mesoporous hybrid materials. The time performance is significantly better, almost by a factor of 10, than in the corresponding {sup 13}C detected experiment. The proposed scheme represents a new analytical tool for studying other solid-state systems and the basis for the development of more advanced 2D and 3D correlation methods.
- Research Organization:
- Ames Lab., Ames, IA (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- DE-AC02-07CH11358
- OSTI ID:
- 962897
- Report Number(s):
- IS-J 7297; TRN: US200916%%329
- Journal Information:
- Journal of Magnetic Resonance, Vol. 196, Issue 1
- Country of Publication:
- United States
- Language:
- English
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