Indirectly detected through-bond chemical shift correlation NMR spectroscopy in solids under fast MAS: Studies of organic-inorganic hybrid materials
Journal Article
·
· Journal of Magnetic Resonance
OSTI ID:962897
Indirectly detected, through-bond NMR correlation spectra between {sup 13}C and {sup 1}H nuclei are reported for the first time in solid state. The capabilities of the new method are demonstrated using naturally abundant organic-inorganic mesoporous hybrid materials. The time performance is significantly better, almost by a factor of 10, than in the corresponding {sup 13}C detected experiment. The proposed scheme represents a new analytical tool for studying other solid-state systems and the basis for the development of more advanced 2D and 3D correlation methods.
- Research Organization:
- Ames Laboratory (AMES), Ames, IA (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC02-07CH11358
- OSTI ID:
- 962897
- Report Number(s):
- IS-J 7297
- Journal Information:
- Journal of Magnetic Resonance, Journal Name: Journal of Magnetic Resonance Journal Issue: 1 Vol. 196; ISSN 1090-7807
- Country of Publication:
- United States
- Language:
- English
Similar Records
Indirectly detected chemical shift correlation NMR spectroscopy in solids under fast magic angle spinning
Characterization of nanostructured organic-inorganic hybrid materials using advanced solid-state NMR spectroscopy
Directly and indirectly detected through-bond heteronuclear correlation solid-state NMR spectroscopy under fast MAS
Thesis/Dissertation
·
Fri Dec 31 23:00:00 EST 2010
·
OSTI ID:1029608
Characterization of nanostructured organic-inorganic hybrid materials using advanced solid-state NMR spectroscopy
Journal Article
·
Fri May 01 00:00:00 EDT 2009
· Materials Research Society Symposia Proceedings
·
OSTI ID:984443
Directly and indirectly detected through-bond heteronuclear correlation solid-state NMR spectroscopy under fast MAS
Journal Article
·
Thu Sep 10 00:00:00 EDT 2009
· Journal of Magnetic Resonance
·
OSTI ID:969050