Speciation of C{sub 6}H{sub 6} isomers by GC-matrix isolation FTIR-MS.
Isomeric C{sub 6}H{sub 6} species produced by high-pressure shock tube pyrolysis of 1,5-hexadiyne have been investigated by gas chromatography-matrix isolation FTIR spectroscopy-mass spectrometry. In addition to benzene (stable end product) and 1,5-hexadiyne (starting material), six isomeric C{sub 6}H{sub 6} species have been identified on the basis of spectroscopic characteristics. The results are consistent with theoretical predictions of stable species that will be formed in the pyrolysis of 1,5-hexadiyne and key species have been positively identified for the first time.
- Research Organization:
- Argonne National Laboratory (ANL)
- Sponsoring Organization:
- SC; NSF
- DOE Contract Number:
- AC02-06CH11357
- OSTI ID:
- 961501
- Report Number(s):
- ANL/CHM/JA-48436
- Journal Information:
- J. Phys. Chem. A, Journal Name: J. Phys. Chem. A Journal Issue: 16 ; 2004 Vol. 108; ISSN 1089-5639; ISSN JPCAFH
- Country of Publication:
- United States
- Language:
- ENGLISH
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