Tribological characteristics of aluminum alloys against steel lubricated by ammonium and imidazolium ionic liquids

Journal Article · Thu Jan 01 04:00:00 EST 2009 · Wear

DOI:https://doi.org/10.1016/j.wear.2008.12.038· OSTI ID:958930

Qu, Jun ^[1]; Blau, Peter Julian ^[1]; Dai, Sheng ^[1]; Luo, Huimin ^[1]; Meyer, III, Harry M ^[1]; Truhan, John J. ^[2]

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1. ORNL
2. Caterpillar Inc.

Sliding friction and wear characteristics of aluminum alloys against AISI 52100 steel lubricated by ionic liquids (ILs) were investigated at both room and elevated temperatures. The tested aluminum alloys include a commercially pure aluminum Al 1100, a wrought alloy Al 6061-T6511, and a cast alloy Al 319-T6. The lubricating performance of two ILs with the same anion, one ammonium-based [C8H17]3NH.Tf2N and one imidazolium-based C10mim.Tf2N, were compared each other and benchmarked against that of a conventional fully-formulated engine oil. Significant friction (up to 35%) and wear (up to 55%) reductions were achieved by the ammonium IL when lubricating the three aluminum alloys compared to the engine oil. The imidazolium IL performed better than the oil but not as well as the ammonium IL for Al 1100 and 319 alloys. However, accelerated wear was unexpectedly observed for Al 6061 alloy when lubricated by C10mim.Tf2N. Surface chemical analyses implied complex tribochemical reactions between the aluminum surfaces and ILs during the wear testing, which has been demonstrated either beneficial by forming a protective boundary film or detrimental by causing severe tribo-corrosion. The effects of the IL cation structure, aluminum alloy composition, and tribo-testing condition on the friction and wear results have been discussed.

• Research Organization: Oak Ridge National Laboratory (ORNL); Shared Research Equipment Collaborative Research Center
• Sponsoring Organization: ORNL LDRD Seed-Money; EE USDOE - Office of Energy Efficiency and Renewable Energy (EE)
• DOE Contract Number: AC05-00OR22725
• OSTI ID: 958930
• Journal Information: Wear, Journal Name: Wear Journal Issue: 5-8 Vol. 267; ISSN 0043-1648; ISSN WEARAH
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
ALLOYS
ALUMINIUM
CATIONS
ENGINES
FRICTION
PERFORMANCE
SLIDING FRICTION
STEELS
TESTING