Development of Palladium L-Edge X-Ray Absorption Spectroscopy And Its Application for Chloropalladium Complexes
Journal Article
·
· Inorg. Chim. Acta 361:1047,2008
OSTI ID:958607
X-ray absorption spectroscopy (XAS) is a synchrotron-based experimental technique that provides information about geometric and electronic structures of transition metal complexes. Combination of metal L-edge and ligand K-edge XAS has the potential to define the complete experimental ground state electronic structures for metal complexes with unoccupied d manifolds. We developed a quantitative treatment for Pd L-edge spectroscopy on the basis of the well-established chlorine K-edge XAS for a series of chloropalladium complexes that are pre-catalysts in various organic transformations. We found that Pd-Cl bonds are highly covalent, such as 24 {+-} 2%, 34 {+-} 3%, and 48 {+-} 4% chloride 3p character for each Pd-Cl bond in [PdCl{sub 4}]{sup 2-}, [PdCl{sub 6}]{sup 2-}, and PdCl{sub 2}, respectively. Pd(2p {yields} 4d) transition dipole integrals of 20.8 (SSRL)/16.9 (ALS) eV and 14.1 (SSRL)/11.9 (ALS) eV were determined using various combinations of L-edges for Pd(II) and Pd(IV), respectively. Application of metal-ligand covalency and transition dipole integrals were demonstrated for the example of bridging chloride ligands in PdCl{sub 2}. Our work lays the foundation for extending the quantitative treatment to other catalytically important ligands, such as phosphine, phosphite, olefin, amine, and alkyl in order to correlate the electronic structures of palladium complexes with their catalytic activity.
- Research Organization:
- Stanford Linear Accelerator Center (SLAC)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC02-76SF00515
- OSTI ID:
- 958607
- Report Number(s):
- SLAC-REPRINT-2009-081
- Journal Information:
- Inorg. Chim. Acta 361:1047,2008, Journal Name: Inorg. Chim. Acta 361:1047,2008 Journal Issue: 4 Vol. 361; ISSN 0020-1693; ISSN ICHAA3
- Country of Publication:
- United States
- Language:
- English
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