Magnon sidebands and spin-charge coupling in bismuth ferrite probed by nonlinear optical spectroscopy.

Journal Article · Thu Jan 01 04:00:00 EST 2009 · Phys. Rev. B

DOI:https://doi.org/10.1103/PhysRevB.79.224106· OSTI ID:958273

Ramirez, M O; Kumar, A; Denev, S A; Podraza, N J; Xu, X S; Rai, R C; Chu, Y H; Seidel, J; Martin, L W; Yang, S -Y; Saiz, E; Ihlefeld, J F; Lee, S; Klug, J; Cheong, S W; Bedzyk, M J; Auciello, O; Schlom, D G; Ramesh, R; Orenstein, J ; Musfeldt, J L; Gopalan, V; LBNL,

The interplay between spin waves (magnons) and electronic structure in materials leads to the creation of additional bands associated with electronic energy levels which are called magnon sidebands. The large difference in the energy scales between magnons (meV) and electronic levels (eV) makes this direct interaction weak and hence makes magnon sidebands difficult to probe. Linear light absorption and scattering techniques at low temperatures are traditionally used to probe these sidebands. Here we show that optical second-harmonic generation, as the lowest-order nonlinear process, can successfully probe the magnon sidebands at room temperature and up to 723 K in bismuth ferrite, associated with large wave vector multimagnon excitations which linear absorption studies are able to resolve only under high magnetic fields and low temperatures. Polarized light studies and temperature dependence of these sidebands reveal a spin-charge coupling interaction of the type P{sub s}L{sup 2} between the spontaneous polarization (P{sub s}) and antiferromagnetic order parameter, L in bismuth ferrite, that persists with short-range correlation well into the paramagnetic phase up to high temperatures. These observations suggest a broader opportunity to probe the collective spin-charge-lattice interactions in a wide range of material systems at high temperatures and electronic energy scales using nonlinear optics.

• Research Organization: Argonne National Laboratory (ANL)
• Sponsoring Organization: SC
• DOE Contract Number: AC02-06CH11357
• OSTI ID: 958273
• Report Number(s): ANL/MSD/JA-64551
• Journal Information: Phys. Rev. B, Journal Name: Phys. Rev. B Journal Issue: 2009 Vol. 79; ISSN 1098-0121
• Country of Publication: United States
• Language: ENGLISH

Related Subjects

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS
ABSORPTION
BISMUTH
ELECTRONIC STRUCTURE
ENERGY LEVELS
FERRITE
HARMONIC GENERATION
MAGNETIC FIELDS
MAGNONS
NONLINEAR OPTICS
ORDER PARAMETERS
POLARIZATION
PROBES
SCATTERING
SPECTROSCOPY
SPIN WAVES
TEMPERATURE DEPENDENCE
VECTORS