Polymer Aging Techniques Applied to Degradation of a Polyurethane Propellant Binder
The oxidative thermal aging of a crosslinked hydroxy-terminated polybutadiene (HTPB)/isophorone diisocyanate (IPDI) polyurethane rubber, commonly used as the polymeric binder matrix in solid rocket propellants, was studied at temperatures of RT to 125 C. We investigate changes in tensile elongation, mechanical hardening, polymer network properties, density, O{sub 2} permeation and molecular chain dynamics using a range of techniques including solvent swelling, detailed modulus profiling and NMR relaxation measurements. Using extensive data superposition and highly sensitive oxygen consumption measurements, we critically evaluate the Arrhenius methodology, which normally assumes a linear extrapolation of high temperature aging data. Significant curvature in the Arrhenius diagram of these oxidation rates was observed similar to previous results found for other rubber materials. Preliminary gel/network properties suggest that crosslinking is the dominant process at higher temperatures. We also assess the importance of other constituents such as ammonium perchlorate or aluminum powder in the propellant formulation.
- Research Organization:
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Sandia National Lab. (SNL-CA), Livermore, CA (United States)
- Sponsoring Organization:
- US Department of Energy (US)
- DOE Contract Number:
- AC04-94AL85000
- OSTI ID:
- 9578
- Report Number(s):
- SAND99-1473C; TRN: AH200124%%327
- Resource Relation:
- Conference: 1999 Life Cycle of Energetic Materials, Orlando, FL (US), 09/26/1999--09/29/1999; Other Information: PBD: 27 Jul 1999
- Country of Publication:
- United States
- Language:
- English
Similar Records
Infrared microspectroscopic study of the thermo-oxidative degradation of hydroxy-terminated polybutadiene/isophorone diisocyanate polyurethane rubber
Condition Monitoring of a Thermally Aged HTPB/IPDI Elastomer by NMR CP Recovery Times