Near-infrared photoluminescence and ligand K-edge x-ray absorption spectroscopies of AnO2Cl42-(An:u, NP, Pu)
Conference
·
OSTI ID:957721
- Los Alamos National Laboratory
We have used photoluminescence and X-ray absorption spectroscopies to investigate electronic structures and metal-ligand bonding of a series of An02CI/ ' (An = U, Np, Pu) compounds. Specifically, we will discuss time-resolved near-infrared emission spectra of crystalline Cs2U(An)02C14 (An = Np and Pu) both at 23 K and 75 K, as well as chlorine Kedge X-ray absorption spectra ofCs2An02CI4 (An = U, Np).
- Research Organization:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC52-06NA25396
- OSTI ID:
- 957721
- Report Number(s):
- LA-UR-08-04307; LA-UR-08-4307; TRN: US1005597
- Resource Relation:
- Conference: Plutonium Futures The Science 2008 ; July 7, 2008 ; Dijon, France
- Country of Publication:
- United States
- Language:
- English
Similar Records
Simulating Cl K-edge X-ray absorption spectroscopy in MCl62- (M= U, Np, Pu) complexes and UOCl5- using time-dependent density functional theory
Covalency in actinide(iv
) hexachlorides in relation to the chlorine K-edge X-ray absorption structure
X-ray absorption edge spectroscopy of ligands bound to open-shell metal ions: Chlorine K-edge studies of covalency in CuCl sub 4 sup 2 minus
Journal Article
·
Fri Feb 21 00:00:00 EST 2014
· Theoretical Chemistry Accounts, 133(4):1-7
·
OSTI ID:957721
Covalency in actinide(
Journal Article
·
Wed Mar 16 00:00:00 EDT 2022
· Chemical Science
·
OSTI ID:957721
X-ray absorption edge spectroscopy of ligands bound to open-shell metal ions: Chlorine K-edge studies of covalency in CuCl sub 4 sup 2 minus
Journal Article
·
Wed Feb 14 00:00:00 EST 1990
· Journal of the American Chemical Society; (USA)
·
OSTI ID:957721