Line Intensities for the v1, v3, and v1 + v3 Bands of 34SO2
Using both high resolution (0.0018 cm-1) and medium resolution ( 0.112 cm-1) Fourier transform spectra of an enriched 34S (95.3%) sample of sulfur dioxide it has been possible to accurately measure a large number of individual line intensities for some of the strongest of the SO2 bands, i.e. ν1, ν3 and ν1+ν3. . These intensities were least squares fitted using a theoretical model which takes into account the vibration-rotation interactions linking the upper energy levels where needed, and, in this way, expansions of the various transition moment operators were determined. The Hamiltonian parameters determined in previous analyses [Lafferty WJ, Flaud J.-M., Sams R.L., Ngom El H A. High resolution analysis of the rotational levels of the (000), (010), (100), (001),(020), (110) and (011) vibrational states of 34S16O2, J. Mol. Spectrosc. (2008), doi:10.1016/j.jms.2008.06.013; Lafferty WJ, Flaud J-M, Ngom El H A, Sams, L. 34S16O2: High resolution analysis of the (030), (101),(111), (002) and (201) vibrational states: Determination of equilibrium rotational constants of sulfur dioxide and anharmonic vibrational constants. J Mol Spectrosc, submitted ] together with these moments were then used to generate synthetic spectra for the bands studied and their corresponding hot bands providing one with an extensive picture of the absorption spectrum of 34SO2 in the spectral domains, 8.7, 7.4 and 4 μm.
- Research Organization:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab. (EMSL)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC05-76RL01830
- OSTI ID:
- 956895
- Report Number(s):
- PNNL-SA-62043; JQSRAE; 21290; KP1504020; TRN: US201007%%11
- Journal Information:
- Journal of Quantitative Spectroscopy and Radiative Transfer, 110(9-10):669-674, Vol. 110, Issue 9-10; ISSN 0022-4073
- Country of Publication:
- United States
- Language:
- English
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