Covalent Metal-Nanotube Heterojunctions as Ultimate Nano-Contacts
- University of Strasbourg, France
- ORNL
- University of Oxford, UK
- Rice University
We report the controlled formation and characterization of heterojunctions between carbon nanotubes and different metal nanocrystals (Fe, Co, Ni, and FeCo). The heterojunctions are formed from metal-filled multiwall carbon nanotubes (MWNTs) via intense electron beam irradiation at temperatures in the range of 450-700 C and observed in situ in a transmission electron microscope. Under irradiation, the segregation of metal and carbon atoms occurs, leading to the formation of heterojunctions between metal and graphite. Metallic conductivity of the metal-nanotube junctions was found by using in situ transport measurements in an electron microscope. Density functional calculations show that these structures are mechanically strong, the bonding at the interface is covalent, and the electronic states at and around the Fermi level are delocalized across the entire system. These properties are essential for the application of such heterojunctions as contacts in electronic devices and vital for the fabrication of robust nanotube-metal composite materials.
- Research Organization:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC05-00OR22725
- OSTI ID:
- 953182
- Journal Information:
- Proceedings of the National Academy of Sciences, Vol. 106, Issue N/A; ISSN 0027-8424
- Country of Publication:
- United States
- Language:
- English
Similar Records
Chemical Strategies for Enhancing Activity and Charge Transfer in Ultrathin Pt Nanowires Immobilized onto Nanotube Supports for the Oxygen Reduction Reaction
Improving mechanical properties of carbon nanotube fibers through simultaneous solid-state cycloaddition and crosslinking