Interaction of Lithium Hydride and Ammonia Borane in THF
Journal Article
·
· Chemical Communications, 43:5595-5597
The two-step reaction between LiH and NH3BH3 in THF leads to the production of more than 14 wt% of hydrogen at 40 °C.In the present study we investigate the reactivity of AB dissolved in tetrahydrofuran (THF) with a suspension of LiH and observe the formation of LiNH2BH3 and enhanced reaction kinetics with an interesting dependence on AB concentration.
- Research Organization:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (US), Environmental Molecular Sciences Laboratory (EMSL)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC05-76RL01830
- OSTI ID:
- 951234
- Report Number(s):
- PNNL-SA-62842; 10491b; 10491; EB4202000
- Journal Information:
- Chemical Communications, 43:5595-5597, Journal Name: Chemical Communications, 43:5595-5597 Vol. 43
- Country of Publication:
- United States
- Language:
- English
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