Pulse radiolysis studies of solvated electrons in supercritical ethane with methanol as cosolvent.
Pulse radiolysis has been used to study the solvated electron in supercritical ethane with methanol as a cosolvent. These measurements give information about the liquid structure of the cosolvent in these systems. The results show that at temperatures below 110 {sup o}C, there are high local concentrations of alcohol molecules (clusters), which are capable of solvating an electron. The agglomeration number of methanol clusters depends on mole fraction of alcohol at a fixed temperature. Addition of salts increases the size of methanol clusters.
- Research Organization:
- Argonne National Laboratory (ANL)
- Sponsoring Organization:
- SC
- DOE Contract Number:
- AC02-06CH11357
- OSTI ID:
- 943265
- Report Number(s):
- ANL/CHM/JA-38736
- Journal Information:
- J. Phys. Chem. A, Journal Name: J. Phys. Chem. A Journal Issue: 30 ; Aug. 2, 2001 Vol. 105; ISSN 1089-5639; ISSN JPCAFH
- Country of Publication:
- United States
- Language:
- ENGLISH
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