The evolution of the boundary layer and its effect on air chemistry in the Phoenix area.
During a 4-week period in May and June of 1998, meteorological and chemical measurements were made as part of a field campaign carried out in the Phoenix area. Data from the field campaign provide the first detailed measurements of the properties of the convective boundary layer in this area and of the effects of these properties on ozone levels. The meteorological and chemical measurements have been combined with results from a set of meteorological, particle, and chemistry models to study ozone production, transport, and mixing in the vicinity of Phoenix. Good agreement between the simulations and observations was obtained, and the results have been used to illustrate several important factors affecting ozone patterns in the region. Heating of the higher terrain north and east of Phoenix regularly produced thermally driven circulations from the south and southwest through most of the boundary layer during the afternoon, carrying the urban ozone plume to the northeast. The combination of deep mixed layers and moderate winds aloft provided good ventilation of the Phoenix area on most days so that multiday buildups of locally produced ozone did not appear to contribute significantly to ozone levels during the study period. Sensitivity simulations determined that 20 to 40% of the afternoon surface ozone mixing ratios (corresponding to 15 to 35 ppb) were due to vertical mixing processes that entrained reservoirs of ozone into the growing convective boundary layer. The model results also indicated that ozone production in the region is volatile organic compound limited.
- Research Organization:
- Argonne National Laboratory (ANL)
- Sponsoring Organization:
- SC
- DOE Contract Number:
- AC02-06CH11357
- OSTI ID:
- 943098
- Report Number(s):
- ANL/ER/JA-37454
- Journal Information:
- J. Geophys. Res., Journal Name: J. Geophys. Res. Journal Issue: D18 ; Sep. 27, 2000 Vol. 105; ISSN JGREA2; ISSN 0148-0227
- Country of Publication:
- United States
- Language:
- ENGLISH
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