Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

On comparison of experimental thermochemical data with G3 theory.

Journal Article · · J. Phys. Chem. A
DOI:https://doi.org/10.1021/jp0026585· OSTI ID:942985

The results of assessments of methods for computing molecular thermochemical data can depend significantly on how comparison with experimental data is done. This is illustrated for two cases involving G3 theory: the energy of SiF{sub 4} and the G2/97 test set.

Research Organization:
Argonne National Laboratory (ANL)
Sponsoring Organization:
SC; NSF
DOE Contract Number:
AC02-06CH11357
OSTI ID:
942985
Report Number(s):
ANL/CHM/JA-36488
Journal Information:
J. Phys. Chem. A, Journal Name: J. Phys. Chem. A Journal Issue: 1 ; Jan. 11, 2001 Vol. 105; ISSN 1089-5639; ISSN JPCAFH
Country of Publication:
United States
Language:
ENGLISH

Similar Records

Gaussian-3 (G3) theory for molecules containing first and second-row atoms
Journal Article · Sat Oct 31 19:00:00 EST 1998 · Journal of Chemical Physics · OSTI ID:663683

Assessment of Gaussian-3 and density functional theories for a larger experimental test set
Journal Article · Mon May 01 00:00:00 EDT 2000 · Journal of Chemical Physics · OSTI ID:20216007

Gaussian-3 theory : a variation based on third-order perturbation theory and an assessment of the contribution of core-related correlation.
Journal Article · Thu Nov 11 19:00:00 EST 1999 · Chem. Phys. Lett. · OSTI ID:942646