Experimental determination of the {nu}{sub 1} fundamental vibrational transition moment for HNC.
Journal Article
·
· Chem. Phys. Lett.
Hydrogen isocyanide, HNC, was generated by the reaction of translationally energetic H atoms with ClCN, and the resulting products, HCl, HCN and HNC, followed by time-resolved infrared absorption spectroscopy. The subsequent reaction of the Cl and CN species with the H atom precursor, CH{sub 3}SH, resulted in a definite stoichiometric relationship between the stable products and HNC. This stoichiometric relationship was used to relate the HNC absorption to those for HCN and HCl. The {nu}{sub 1} fundamental vibrational transition moment was determined to be 0.141{+-}0.007 Debye.
- Research Organization:
- Argonne National Laboratory (ANL)
- Sponsoring Organization:
- ER
- DOE Contract Number:
- AC02-06CH11357
- OSTI ID:
- 942324
- Report Number(s):
- ANL/CHM/JA-30340
- Journal Information:
- Chem. Phys. Lett., Journal Name: Chem. Phys. Lett. Journal Issue: 1-2 ; Feb. 19, 1999 Vol. 301; ISSN CHPLBC; ISSN 0009-2614
- Country of Publication:
- United States
- Language:
- ENGLISH
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