Dynamic investigation of gold nanocrystal assembly using in situ grazing-incidence small angle x-ray scattering.
Here we investigate the dynamic self-assembly pathway of ordered gold nanocrystal arrays during the self-assembly of gold nanocrystal micelles, with and without the presence of colloidal silica precursors, using grazing-incidence X-ray scattering performed at a synchrotron source. With silica precursors present, a lattice with rhombohedral symmetry is formed from the partial collapse of a face-centered cubic structure. In the absence of silica, a transient body-centered orthorhombic phase appears, which rapidly collapses into a glassy nanocrystal film. The appearance of face-centered and body-centered structures is consistent with a phase diagram for charged colloidal particles with assembly modulated via Coulomb screening.
- Research Organization:
- Argonne National Laboratory (ANL)
- Sponsoring Organization:
- SC; NNSA; NSF
- DOE Contract Number:
- AC02-06CH11357
- OSTI ID:
- 940955
- Report Number(s):
- ANL/XSD/JA-62961
- Journal Information:
- Langmuir, Journal Name: Langmuir Journal Issue: 2008 Vol. 24; ISSN LANGD5; ISSN 0743-7463
- Country of Publication:
- United States
- Language:
- ENGLISH
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