Melting of Copper and Nickel at high pressure: the role of d-electrons

Journal Article · Mon Apr 11 04:00:00 EDT 2005 · Physical Review Letters

OSTI ID:936448

Japel, S; Boehler, R; Ross, M

Melting curves of Cu and Ni were measured to 97 GPa (3800 K) and 60 GPa (2970 K), respectively, in the laser-heated diamond cell. The measured melting temperatures of Cu are in good agreement with recent theoretical calculations. The melting slope (dT/dP) of Cu, which has a filled d-electron band, is about 2.5 times steeper than for Ni, which with one less electron, has a partially unfilled d-electron band. The relatively low melting slope obtained for Ni, measured using identical experimental methods as for Cu, is consistent with our previous measurements for other transition metals with partially filled d-bands, which are in serious disagreement with theoretical estimates. The present results confirm the key role d-shell electrons play in determining the high pressure melting curves.

• Research Organization: Lawrence Livermore National Laboratory (LLNL), Livermore, CA
• Sponsoring Organization: USDOE
• DOE Contract Number: W-7405-ENG-48
• OSTI ID: 936448
• Report Number(s): UCRL-JRNL-211837
• Journal Information: Physical Review Letters, Journal Name: Physical Review Letters Vol. 95; ISSN 0031-9007; ISSN PRLTAO
• Country of Publication: United States
• Language: English

Related Subjects

71 CLASSICAL AND QUANTUM MECHANICS
GENERAL PHYSICS
COPPER
DIAMONDS
ELECTRONS
MELTING
NICKEL
TRANSITION ELEMENTS