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Silica-Supported Tantalum Clusters: Catalyst for Alkane Conversion

Journal Article · · Chemical Communications
DOI:https://doi.org/10.1039/b608794a· OSTI ID:930242
Silica-supported tantalum clusters (on average, approximately tritantalum) were formed by the treatment, in either H{sub 2} or ethane, of adsorbed Ta(CH{sub 2}Ph){sub 5}; the supported catalyst is active for ethane conversion to methane and propane at 523 K, with the used catalyst containing clusters of the same average nuclearity as the precursor.
Research Organization:
Brookhaven National Laboratory (BNL) National Synchrotron Light Source
Sponsoring Organization:
Doe - Office Of Science
DOE Contract Number:
AC02-98CH10886
OSTI ID:
930242
Report Number(s):
BNL--80924-2008-JA
Journal Information:
Chemical Communications, Journal Name: Chemical Communications Vol. 38
Country of Publication:
United States
Language:
English

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