Cationic Zinc-Cadmium Alloy Clusters in Zeolite A
Journal Article
·
· Microporous and Mesoporous Materials
Rietveld analysis of synchrotron powder X-ray diffraction data obtained from the product of the reaction of cadmium vapor with dehydrated zinc-exchanged zeolite A (LTA structure type) indicates the formation of cationic zinc-cadmium alloy clusters. The clusters are located in approximately 40% of the sodalite cages; the remaining 60% of the cages contain divalent zinc ions coordinated both to the oxygen atoms of the zeolite framework and to residual extra framework oxygen.
- Research Organization:
- Brookhaven National Laboratory (BNL) National Synchrotron Light Source
- Sponsoring Organization:
- Doe - Office Of Science
- DOE Contract Number:
- AC02-98CH10886
- OSTI ID:
- 929986
- Report Number(s):
- BNL--80595-2008-JA
- Journal Information:
- Microporous and Mesoporous Materials, Journal Name: Microporous and Mesoporous Materials Vol. 104
- Country of Publication:
- United States
- Language:
- English
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