Ionic liquids for rechargeable lithium batteries

Technical Report · Thu Sep 29 04:00:00 EDT 2005

DOI:https://doi.org/10.2172/929086· OSTI ID:929086

Salminen, Justin; Papaiconomou, Nicolas; Kerr, John; Prausnitz, John; Newman, John

We have investigated possible anticipated advantages of ionic-liquid electrolytes for use in lithium-ion batteries. Thermal stabilities and phase behavior were studied by thermal gravimetric analysis and differential scanning calorimetry. The ionic liquids studied include various imidazoliumTFSI systems, pyrrolidiniumTFSI, BMIMPF{sub 6}, BMIMBF{sub 4}, and BMIMTf. Thermal stabilities were measured for neat ionic liquids and for BMIMBF{sub 4}-LiBF{sub 4}, BMIMTf-LiTf, BMIMTFSI-LiTFSI mixtures. Conductivities have been measured for various ionic-liquid lithium-salt systems. We show the development of interfacial impedance in a Li|BMIMBF{sub 4} + LiBF{sub 4}|Li cell and we report results from cycling experiments for a Li|BMIMBF{sub 4} + 1 mol/kg LIBF{sub 4}|C cell. The interfacial resistance increases with time and the ionic liquid reacts with the lithium electrode. As expected, imidazolium-based ionic liquids react with lithium electrodes. We seek new ionic liquids that have better chemical stabilities.

• Research Organization: COLLABORATION - UCBerkeley
• Sponsoring Organization: USDOE Director. Office of Science. Basic EnergySciences
• DOE Contract Number: AC02-05CH11231
• OSTI ID: 929086
• Report Number(s): LBNL--58901; BnR: KC0302040
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
CALORIMETRY
ELECTRODES
ELECTROLYTES
IMPEDANCE
LITHIUM
MIXTURES
THERMAL GRAVIMETRIC ANALYSIS