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Rapid Synthesis and Size Control of CuInS2 Semi-Conductor Nanoparticles Using Microwave Irradiation

Journal Article · · Journal of Nanoparticle Research, 10(4):633-641
The properties of CuInS2 semi-conductor nanoparticles make them attractive materials for use in next-generation photovoltaics. We have prepared CuInS2 nanoparticles from single source precursors via microwave irradiation. Microwave irradiation methods have allowed us to increase the efficiency of preparation of these materials by providing uniform heating and rapid reaction times. We have also controlled nanoparticle growth in the 3 to 5 nm size range by varying thiolated capping ligand concentrations as well as reaction temperatures and times. Investigation of the photophysical properties of the colloidal nanoparticles were performed using electronic absorption and luminescence emission spectroscopy. Qualitative nanoparticles sizes were determined from the photoluminescence (PLE) data and compared to HRTEM images.
Research Organization:
Pacific Northwest National Laboratory (PNNL), Richland, WA (US), Environmental Molecular Sciences Laboratory (EMSL)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-76RL01830
OSTI ID:
927703
Report Number(s):
PNNL-SA-53414; 17795; KP1704020
Journal Information:
Journal of Nanoparticle Research, 10(4):633-641, Journal Name: Journal of Nanoparticle Research, 10(4):633-641
Country of Publication:
United States
Language:
English

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