SYNTHESIS OF MONO-, DI-, AND POLYNITROXIDES. CLASSIFICATION OF ESRSPECTRA OF FLEXIBLE DINITROXIDES DISSOLVED IN LIQUIDS AND GLASSES

Journal Article · Sat Nov 01 00:00:00 EST 1969 · Journal of the American Chemical Society

OSTI ID:927399

Ferruti, P; Gill, D; Klein, M P; Wang, H H; Entine, G; Calvin, M

The synthesis of flexible biradical strain-gauges which could be anchored onto two sites of a deformable biological structure had been attempted. Qualitative relationships between the possible conformations of the biradicals and the observed ESR spectra provide guidelines for further synthetic work. Some of the nitroxides synthesized and characterized are: R-CO-R{sub 1}-N-(CH{sub 2}){sub n}-R{sub 2}-N-CO-R, where R is 1-oxyl-2,2,6,6-tetramethyl pyrroline bonded at the 3-position, n = 2,3 and R{sub 1,2} = -H; -C{sub 18}{sub 37}; -CH{sub 2}COOH; -CH{sub 2}COOC{sub 2}H{sub 5}; -CH{sub 2}CONH(CH{sub 2}){sub 2}N(CH{sub 3}){sub 2}; -CH{sub 2}CONH(CH{sub 2}){sub 2}N{sup +}(CH{sub 3}) -CH{sub 2}CO-imidazolide.

• Research Organization: Ernest Orlando Lawrence Berkeley NationalLaboratory, Berkeley, CA (US)
• Sponsoring Organization: USAEC
• DOE Contract Number: AC02-05CH11231
• OSTI ID: 927399
• Report Number(s): UCRL--19419
• Journal Information: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 0 Vol. 0; ISSN JACSAT; ISSN 0002-7863
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
CLASSIFICATION
ELECTRON SPIN RESONANCE
NITROGEN OXIDES
SPECTRA
SYNTHESIS