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Picosecond x-ray absorption spectroscopy of photochemical transient species in solution

Conference ·
OSTI ID:925912

A photoinduced Fe(II) spin crossover reaction in solution is studied with ultrafast x-ray absorption spectroscopy. The iron-nitrogen bond lengthens by 0.21+-0.03 Angstrom in the high-spin transient excited state relative to the ground state.

Research Organization:
Ernest Orlando Lawrence Berkeley National Laboratory, Berkeley, CA (US)
Sponsoring Organization:
Chemical Sciences Division
DOE Contract Number:
AC02-05CH11231
OSTI ID:
925912
Report Number(s):
LBNL--93E
Country of Publication:
United States
Language:
English