Oxidation reactivity channels for 2-(pyridin-2-yl)-N,N-diphenylacetamides
Journal Article
·
· Journal of Organic Chemistry, 72(4):9195-9202
Synthetic routes to 2-(pyridin-2-yl)-N,N-diphenylacetamide and 2-(6-methylpyridin-2-yl)-N,N-diphenylacetamide are described along with results from the chemical oxidation of these compounds with peracetic acid, m-chloroperbenzoic acid, and OXONE. In each case, oxidations generate four products in varying amounts depending on the oxidant and reaction conditions. Each product has been characterized by spectroscopic methods and the molecular structures of several of the new compounds have been confirmed by X-ray crystallography.
- Research Organization:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (US)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC05-76RL01830
- OSTI ID:
- 922894
- Report Number(s):
- PNNL-SA-58743
- Journal Information:
- Journal of Organic Chemistry, 72(4):9195-9202, Journal Name: Journal of Organic Chemistry, 72(4):9195-9202 Journal Issue: 4 Vol. 72; ISSN 0022-3263; ISSN JOCEAH
- Country of Publication:
- United States
- Language:
- English
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