Synthesis and Characterization of Et2NM OB[Si(OtBu)3]2 3 (M=Zr,Hf) Molecular Precursors to Zr/B/Si/O and Hf/B/Si/O Materials
Journal Article
·
· Zeitschrift fur Anorganische und AllgemeineChemie
Two new transition metal complexes containing the -OB[OSi(OtBu)3]2 ligand, Et2NM{l_brace}OB[OSi(OtBu)3]2{r_brace}3 (M = Zr, Hf), are reported. These species are the 4th and 5th examples of complexes containing this recently reported borosiloxide ligand. Their use as potential molecular precursors to multi-component oxide materials via the thermolytic molecular precursor (TMP) method is discussed.
- Research Organization:
- Ernest Orlando Lawrence Berkeley NationalLaboratory, Berkeley, CA (US)
- Sponsoring Organization:
- USDOE Director. Office of Science. Basic EnergySciences
- DOE Contract Number:
- AC02-05CH11231
- OSTI ID:
- 919830
- Report Number(s):
- LBNL--59611; BnR: KC0302010
- Journal Information:
- Zeitschrift fur Anorganische und AllgemeineChemie, Journal Name: Zeitschrift fur Anorganische und AllgemeineChemie Vol. 631; ISSN 0044-2313; ISSN ZAACAB
- Country of Publication:
- United States
- Language:
- English
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