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Title: Natural and industrial analogues for leakage of CO2 from storagereservoirs: identification of features, events, and processes and lessonslearned

Abstract

The injection and storage of anthropogenic CO2 in deepgeologic formations is a potentially feasible strategy to reduce CO2emissions and atmospheric concentrations. While the purpose of geologiccarbon storage is to trap CO2 underground, CO2 could migrate away fromthe storage site into the shallow subsurface and atmosphere if permeablepathways such as well bores or faults are present. Large-magnitudereleases of CO2 have occurred naturally from geologic reservoirs innumerous volcanic, geothermal, and sedimentary basin settings. Carbondioxide and natural gas have also been released from geologic CO2reservoirs and natural gas storage facilities, respectively, due toinfluences such as well defects and injection/withdrawal processes. Thesesystems serve as natural and industrial analogues for the potentialrelease of CO2 from geologic storage reservoirs and provide importantinformation about the key features, events, and processes (FEPs) that areassociated with releases, as well as the health, safety, andenvironmental consequences of releases and mitigation efforts that can beapplied. We describe a range of natural releases of CO2 and industrialreleases of CO2 and natural gas in the context of these characteristics.Based on this analysis, several key conclusions can be drawn, and lessonscan be learned for geologic carbon storage. First, CO2 can bothaccumulate beneath, and be released from, primary and secondaryreservoirs with capping units located atmore » a wide range of depths. Bothprimary and secondary reservoir entrapments for CO2 should therefore bewell characterized at storage sites. Second, many natural releases of CO2have been correlated with a specific event that triggered the release,such as magmatic fluid intrusion or seismic activity. The potential forprocesses that could cause geomechanical damage to sealing cap rocks andtrigger the release of CO2 from a storage reservoir should be evaluated.Third, unsealed fault and fracture zones may act as fast and directconduits for CO2 flow from depth to the surface. Risk assessment shouldtherefore emphasize determining the potential for and nature of CO2migration along these structures. Fourth, wells that are structurallyunsound have the potential to rapidly release large quantities of CO2 tothe atmosphere. Risk assessment should therefore be focused on thepotential for both active and abandoned wells at storage sites totransport CO2 to the surface, particularly at sites with depleted oil orgas reservoirs where wellsare abundant. Fifth, the style of CO2 releaseat the surface varies widely between and within different leakage sites.In rare circumstances, the release of CO2 can be a self-enhancing and/oreruptive process; this possibility should be assessed in the case of CO2leakage from storage reservoirs. Sixth, the hazard to human health hasbeen small in most cases of large surface releases of CO2. This could bedue to implementation of public education and CO2 monitoring programs;these programs should therefore be employed to minimize potential health,safety, and environmental effects associated with CO2 leakage. Finally,while changes in groundwater chemistry were related to CO2 leakage due toacidification and interaction with host rocks along flow paths, watersremained potable in most cases. Groundwaters should be monitored forchanges that may be associated with storage reservoirleakage.« less

Authors:
; ;
Publication Date:
Research Org.:
Ernest Orlando Lawrence Berkeley NationalLaboratory, Berkeley, CA (US)
Sponsoring Org.:
USDOE Director, Office of Science; Environmental ProtectionAgency
OSTI Identifier:
919752
Report Number(s):
LBNL-59784
R&D Project: G4W009; BnR: 400408000; TRN: US200822%%516
DOE Contract Number:
DE-AC02-05CH11231; EPA:DE-AC02-05CH11231
Resource Type:
Journal Article
Resource Relation:
Journal Name: Environmental Geology; Journal Volume: 52; Journal Issue: 3; Related Information: Journal Publication Date: 04/2007
Country of Publication:
United States
Language:
English
Subject:
54 ENVIRONMENTAL SCIENCES; ABANDONED WELLS; CAP ROCK; CARBON; CARBON DIOXIDE; ENVIRONMENTAL EFFECTS; GEOLOGIC FORMATIONS; NATURAL GAS; RISK ASSESSMENT; SEDIMENTARY BASINS; STORAGE; STORAGE FACILITIES

Citation Formats

Lewicki, Jennifer L., Birkholzer, Jens, and Tsang, Chin-Fu. Natural and industrial analogues for leakage of CO2 from storagereservoirs: identification of features, events, and processes and lessonslearned. United States: N. p., 2006. Web.
Lewicki, Jennifer L., Birkholzer, Jens, & Tsang, Chin-Fu. Natural and industrial analogues for leakage of CO2 from storagereservoirs: identification of features, events, and processes and lessonslearned. United States.
Lewicki, Jennifer L., Birkholzer, Jens, and Tsang, Chin-Fu. Tue . "Natural and industrial analogues for leakage of CO2 from storagereservoirs: identification of features, events, and processes and lessonslearned". United States. doi:. https://www.osti.gov/servlets/purl/919752.
@article{osti_919752,
title = {Natural and industrial analogues for leakage of CO2 from storagereservoirs: identification of features, events, and processes and lessonslearned},
author = {Lewicki, Jennifer L. and Birkholzer, Jens and Tsang, Chin-Fu},
abstractNote = {The injection and storage of anthropogenic CO2 in deepgeologic formations is a potentially feasible strategy to reduce CO2emissions and atmospheric concentrations. While the purpose of geologiccarbon storage is to trap CO2 underground, CO2 could migrate away fromthe storage site into the shallow subsurface and atmosphere if permeablepathways such as well bores or faults are present. Large-magnitudereleases of CO2 have occurred naturally from geologic reservoirs innumerous volcanic, geothermal, and sedimentary basin settings. Carbondioxide and natural gas have also been released from geologic CO2reservoirs and natural gas storage facilities, respectively, due toinfluences such as well defects and injection/withdrawal processes. Thesesystems serve as natural and industrial analogues for the potentialrelease of CO2 from geologic storage reservoirs and provide importantinformation about the key features, events, and processes (FEPs) that areassociated with releases, as well as the health, safety, andenvironmental consequences of releases and mitigation efforts that can beapplied. We describe a range of natural releases of CO2 and industrialreleases of CO2 and natural gas in the context of these characteristics.Based on this analysis, several key conclusions can be drawn, and lessonscan be learned for geologic carbon storage. First, CO2 can bothaccumulate beneath, and be released from, primary and secondaryreservoirs with capping units located at a wide range of depths. Bothprimary and secondary reservoir entrapments for CO2 should therefore bewell characterized at storage sites. Second, many natural releases of CO2have been correlated with a specific event that triggered the release,such as magmatic fluid intrusion or seismic activity. The potential forprocesses that could cause geomechanical damage to sealing cap rocks andtrigger the release of CO2 from a storage reservoir should be evaluated.Third, unsealed fault and fracture zones may act as fast and directconduits for CO2 flow from depth to the surface. Risk assessment shouldtherefore emphasize determining the potential for and nature of CO2migration along these structures. Fourth, wells that are structurallyunsound have the potential to rapidly release large quantities of CO2 tothe atmosphere. Risk assessment should therefore be focused on thepotential for both active and abandoned wells at storage sites totransport CO2 to the surface, particularly at sites with depleted oil orgas reservoirs where wellsare abundant. Fifth, the style of CO2 releaseat the surface varies widely between and within different leakage sites.In rare circumstances, the release of CO2 can be a self-enhancing and/oreruptive process; this possibility should be assessed in the case of CO2leakage from storage reservoirs. Sixth, the hazard to human health hasbeen small in most cases of large surface releases of CO2. This could bedue to implementation of public education and CO2 monitoring programs;these programs should therefore be employed to minimize potential health,safety, and environmental effects associated with CO2 leakage. Finally,while changes in groundwater chemistry were related to CO2 leakage due toacidification and interaction with host rocks along flow paths, watersremained potable in most cases. Groundwaters should be monitored forchanges that may be associated with storage reservoirleakage.},
doi = {},
journal = {Environmental Geology},
number = 3,
volume = 52,
place = {United States},
year = {Tue Feb 28 00:00:00 EST 2006},
month = {Tue Feb 28 00:00:00 EST 2006}
}
  • The injection and storage of anthropogenic CO{sub 2} in deep geologic formations is a potentially feasible strategy to reduce CO{sub 2} emissions and atmospheric concentrations. While the purpose of geologic carbon storage is to trap CO{sub 2} underground, CO{sub 2} could migrate away from the storage site into the shallow subsurface and atmosphere if permeable pathways such as well bores or faults are present. Large-magnitude releases of CO{sub 2} have occurred naturally from geologic reservoirs in numerous volcanic, geothermal, and sedimentary basin settings. Carbon dioxide and natural gas have also been released from geologic CO{sub 2} reservoirs and natural gasmore » storage facilities, respectively, due to influences such as well defects and injection/withdrawal processes. These systems serve as natural and industrial analogues for the potential release of CO{sub 2} from geologic storage reservoirs and provide important information about the key features, events, and processes (FEPs) that are associated with releases, as well as the health, safety, and environmental consequences of releases and mitigation efforts that can be applied. We describe a range of natural releases of CO{sub 2} and industrial releases of CO{sub 2} and natural gas in the context of these characteristics. Based on this analysis, several key conclusions can be drawn, and lessons can be learned for geologic carbon storage. First, CO{sub 2} can both accumulate beneath, and be released from, primary and secondary reservoirs with capping units located at a wide range of depths. Both primary and secondary reservoir entrapments for CO{sub 2} should therefore be well characterized at storage sites. Second, many natural releases of CO{sub 2} have been correlated with a specific event that triggered the release, such as magmatic fluid intrusion or seismic activity. The potential for processes that could cause geomechanical damage to sealing cap rocks and trigger the release of CO{sub 2} from a storage reservoir should be evaluated. Third, unsealed fault and fracture zones may act as fast and direct conduits for CO{sub 2} flow from depth to the surface. Risk assessment should therefore emphasize determining the potential for and nature of CO{sub 2} migration along these structures. Fourth, wells that are structurally unsound have the potential to rapidly release large quantities of CO{sub 2} to the atmosphere. Risk assessment should therefore be focused on the potential for both active and abandoned wells at storage sites to transport CO{sub 2} to the surface, particularly at sites with depleted oil or gas reservoirs where wells are abundant. Fifth, the style of CO{sub 2} release at the surface varies widely between and within different leakage sites. In rare circumstances, the release of CO{sub 2} can be a self-enhancing and/or eruptive process; this possibility should be assessed in the case of CO{sub 2} leakage from storage reservoirs. Sixth, the hazard to human health has been small in most cases of large surface releases of CO{sub 2}. This could be due to implementation of public education and CO{sub 2} monitoring programs; these programs should therefore be employed to minimize potential health, safety, and environmental effects associated with CO{sub 2} leakage. Finally, while changes in groundwater chemistry were related to CO{sub 2} leakage due to acidification and interaction with host rocks along flow paths, waters remained potable in most cases. Groundwaters should be monitored for changes that may be associated with storage reservoir leakage.« less
  • To study potential ecological impacts of CO{sub 2} leakage to shallow groundwater and soil/sediments from geologic CO{sub 2} sequestration (GCS) sites, this work investigated the viability and metal reduction of Shewanella oneidensis MR-1 under CO{sub 2} stress. While MR-1 could grow under high-pressure nitrogen gas (500 psi), the mix of 1% CO{sub 2} with N{sub 2 at total pressures of 15 or 150 psi significantly suppressed the growth of MR-1, compared to the N{sub 2} control. When CO{sub 2} partial pressures were over 15 psi, the growth of MR-1 stopped. The reduced bacterial viability was consistent with the pH decreasemore » and cellular membrane damage under high pressure CO{sub 2}. After exposure to 150 psi CO{sub 2} for 5 h, no viable cells survived, the cellular contents were released, and microscopy images confirmed significant cell structure deformation. However, after a relatively short exposure (25 min) to 150 psi CO{sub 2}, MR-1 could fully recover their growth within 24 h after the stress was removed, and the reduction of MnO{sub 2} by MR-1 was observed right after the stress was removed. Furthermore, MR-1 survived better if the cells were aggregated rather than suspended, or if pH buffering minerals, such as calcite, were present. To predict the cell viability under different CO{sub 2} pressures and exposure times, a two-parameter mathematical model was developed.« less
  • 4-Aminothiazolyl analogues of the antibiotic natural product GE2270 A (1) were designed, synthesized, and optimized for their activity against Gram positive bacterial infections. Optimization efforts focused on improving the physicochemical properties (e.g., aqueous solubility and chemical stability) of the 4-aminothiazolyl natural product template while improving the in vitro and in vivo antibacterial activity. Structure-activity relationships were defined, and the solubility and efficacy profiles were improved over those of previous analogues and 1. These studies identified novel, potent, soluble, and efficacious elongation factor-Tu inhibitors, which bear cycloalkylcarboxylic acid side chains, and culminated in the selection of development candidates amide 48 andmore » urethane 58.« less