Adsorption Mechanism of Arsenic on Nanocrystalline Titanium Dioxide

Journal Article · Sun Jan 01 04:00:00 EST 2006 · Environ. Sci. Tech.

DOI:https://doi.org/10.1021/es052040e· OSTI ID:914201

Pena, M; Meng, X; Korfiatis, G; Jing, C

Arsenate [As(V)] and arsenite [As(III)] interactions at the solid-water interface of nanocrystalline TiO{sub 2} were investigated using electrophoretic mobility (EM) measurements, Fourier transform infrared (FTIR) spectroscopy, extended X-ray absorption fine structure (EXAFS) spectroscopy, and surface complexation modeling. The adsorption of As(V) and As(III) decreased the point of zero charge of TiO{sub 2} from 5.8 to 5.2, suggesting the formation of negatively charged inner-sphere surface complexes for both arsenic species. The EXAFS analyses indicate that both As(V) and As(III) form bidentate binuclear surface complexes as evidenced by an average Ti-As(V) bond distance of 3.30 Angstroms and Ti-As(III) bond distance of 3.35 Angstroms. The FTIR bands caused by vibrations of the adsorbed arsenic species remained at the same energy levels at different pH values. Consequently, the surface complexes on TiO{sub 2} maintained the same nonprotonated speciation at pH values from 5 to 10, and the dominant surface species were (TiO){sub 2}AsO2- and (TiO){sub 2}AsO{sup -} for As(V) and As(III), respectively. The surface configurations constrained with the spectroscopic results were formulated in the diffuse layer model to describe the adsorption behavior of As in the pH range between 4 and 12. The study suggests that TiO{sub 2} is an effective adsorbent for As removal due to its high surface area and the presence of high affinity surface hydroxyl groups.

• Research Organization: Brookhaven National Laboratory (BNL) National Synchrotron Light Source
• Sponsoring Organization: Doe - Office Of Science
• DOE Contract Number: AC02-98CH10886
• OSTI ID: 914201
• Report Number(s): BNL--78769-2007-JA
• Journal Information: Environ. Sci. Tech., Journal Name: Environ. Sci. Tech. Vol. 40; ISSN ESTHAG; ISSN 0013-936X
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
54 ENVIRONMENTAL SCIENCES
ADSORBENTS
ADSORPTION
AFFINITY
ARSENATES
ARSENIC
CHEMICAL BONDS
NANOSTRUCTURES
REMOVAL
SORPTIVE PROPERTIES
TITANIUM OXIDES
national synchrotron light source