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High pressure x-ray diffraction study of tungsten disulfide

Journal Article · · J. Phys. Chem. Solids

Synchrotron X-ray diffraction was used in conjunction with a diamond anvil cell to investigate the properties of tungsten disulfide (WS{sub 2}) to 25.5 GPa at room temperature. No pressure medium was used to generate hydrostatic pressure. No phase transformation was observed in the pressure range studied. By fitting the pressure-volume data to the third-order Birch-Murnaghan equation of state, the bulk modulus was determined to be K{sub 0T}=61{+-}1 GPa with its pressure derivative K{prime}{sub 0T}=9.0{+-}0.3. It is also found that the c-direction of the hexagonal structure is much more compressible than the a-direction.

Research Organization:
Brookhaven National Laboratory (BNL) National Synchrotron Light Source
Sponsoring Organization:
Doe - Office Of Science
DOE Contract Number:
AC02-98CH10886
OSTI ID:
914178
Report Number(s):
BNL--78746-2007-JA
Journal Information:
J. Phys. Chem. Solids, Journal Name: J. Phys. Chem. Solids Vol. 67; ISSN 0022-3697; ISSN JPCSAW
Country of Publication:
United States
Language:
English

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