Oxidation, Volatilization, and Redistribution of Molybdenum from TZM Alloy in Air
The excellent high temperature strength and thermal conductivity of molybdenum-base alloys provide attractive features for components in advanced magnetic and inertial fusion devices. Refractory metal alloys react readily with oxygen and other gases. Oxidized molybdenum in turn is susceptible to losses from volatile molybdenum trioxide species, (MoO3)m, in air and the hydroxide, MoO2(OH)2, formed from water vapor. Transport of radioactivity by the volatilization, migration, and re-deposition of these volatile species during a potential accident involving a loss of vacuum or inert environment represents a safety issue. In this report we present experimental results on the oxidation, volatilization and re-deposition of molybdenum from TZM in flowing air between 400 and 800°C. These results are compared with calculations obtained from a vaporization mass transfer model using chemical thermodynamic data for vapor pressures of MoO3(g) over pure solid MoO3 and an expression for the vapor pressures of MoO2(OH)2 from the literature. Calculations correlate well with experimental data.
- Research Organization:
- Idaho National Laboratory (INL)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC07-99ID13727
- OSTI ID:
- 911479
- Report Number(s):
- INEEL/EXT-99-01353
- Country of Publication:
- United States
- Language:
- English
Similar Records
Oxidation, volatilization, and redistribution of molybdenum from TZM alloy in air
Oxidation and volatilization of TZM alloy in air