skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Second Generation Advanced Reburning for High Efficiency NOx Control

Abstract

This project is designed to develop a family of novel NO{sub x} control technologies, called Second Generation Advanced Reburning (SGAR) which has the potential to achieve 90+% NO{sub x} control in coal-fired boilers at a significantly lower cost than SCR. The twelfth reporting period in Phase II (July 3-October 15, 2000) included design validation AR-Lean tests (Task No.2.6) in the 10 x 10{sup 6} Btu/hr Tower Furnace. The objective of tests was to determine the efficiency of AR-Lean at higher than optimum OFA/N-Agent injection temperatures in large pilot-scale combustion facility. Tests demonstrated that co-injection of urea with overfire air resulted in NO{sub x} reduction. However, observed NO{sub x} reduction was smaller than that under optimum conditions.

Authors:
; ; ; ; ; ;
Publication Date:
Research Org.:
Energy & Env Research Corp
Sponsoring Org.:
USDOE
OSTI Identifier:
910162
DOE Contract Number:
AC22-95PC95251
Resource Type:
Technical Report
Country of Publication:
United States
Language:
English
Subject:
01 COAL, LIGNITE, AND PEAT; AIR POLLUTION CONTROL; NITROGEN OXIDES; BOILERS; COAL; COMBUSTION; DESIGN; UREA; EXHAUST GASES; RECYCLING

Citation Formats

Roy Payne, Lary Swanson, Antonio Marquez, Ary Chang, Vladimir M. Zamansky, Pete M. Maly, and Vitali V. Lissianski. Second Generation Advanced Reburning for High Efficiency NOx Control. United States: N. p., 2000. Web. doi:10.2172/910162.
Roy Payne, Lary Swanson, Antonio Marquez, Ary Chang, Vladimir M. Zamansky, Pete M. Maly, & Vitali V. Lissianski. Second Generation Advanced Reburning for High Efficiency NOx Control. United States. doi:10.2172/910162.
Roy Payne, Lary Swanson, Antonio Marquez, Ary Chang, Vladimir M. Zamansky, Pete M. Maly, and Vitali V. Lissianski. Sat . "Second Generation Advanced Reburning for High Efficiency NOx Control". United States. doi:10.2172/910162. https://www.osti.gov/servlets/purl/910162.
@article{osti_910162,
title = {Second Generation Advanced Reburning for High Efficiency NOx Control},
author = {Roy Payne and Lary Swanson and Antonio Marquez and Ary Chang and Vladimir M. Zamansky and Pete M. Maly and Vitali V. Lissianski},
abstractNote = {This project is designed to develop a family of novel NO{sub x} control technologies, called Second Generation Advanced Reburning (SGAR) which has the potential to achieve 90+% NO{sub x} control in coal-fired boilers at a significantly lower cost than SCR. The twelfth reporting period in Phase II (July 3-October 15, 2000) included design validation AR-Lean tests (Task No.2.6) in the 10 x 10{sup 6} Btu/hr Tower Furnace. The objective of tests was to determine the efficiency of AR-Lean at higher than optimum OFA/N-Agent injection temperatures in large pilot-scale combustion facility. Tests demonstrated that co-injection of urea with overfire air resulted in NO{sub x} reduction. However, observed NO{sub x} reduction was smaller than that under optimum conditions.},
doi = {10.2172/910162},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sat Sep 30 00:00:00 EDT 2000},
month = {Sat Sep 30 00:00:00 EDT 2000}
}

Technical Report:

Save / Share:
  • This project is designed to develop a family of novel NO{sub x} control technologies, called Second Generation Advanced Reburning which has the potential to achieve 90+% NO{sub x} control in coal fired boilers at a significantly lower cost than SCR. The third reporting period in Phase II (April 1--June 30, 1998) included experimental activities at pilot scale and comparison of the results with full-scale data. The pilot scale tests were performed with the objective of simulating furnace conditions of ongoing full-scale tests at the Greenidge boiler No. 6 owned and operated by NYSEG and defining the processes controlling AR performancemore » to subsequently improve the performance. The tests were conducted in EER' s Boiler Simulator Facility. The main fuel pulsing system was used at the BSF to control the degree of unmixedness, thus providing control over furnace gas O{sub 2} and CO concentrations. Results on AR-Lean, presented in the previous quarterly report, were compared with full-scale data. Performance of reburn+SNCR was tested to predict NO{sub x} control at Greenidge. The results of the BSF reburn+SNCR simulation tests demonstrated that there are synergistic advantages of using these two technologies in series. In particular, injection of overfire air provides additional mixing that reduces negative effects on AR performance at the temperature regime of the Greenidge boiler.« less
  • This project is designed to develop a family of novel NO{sub x} control technologies, called Second Generation Advanced Reburning which has the potential to achieve 90+% NO{sub x} control in coal fired boilers at a significantly lower cost than SCR. The fourth reporting period in Phase II (July 1--September 30, 1998) included experimental activities at pilot scale and combined chemistry-mixing modeling on gas reburning. The pilot scale tests reported in previous Quarterly Reports QR-2 and QR-3 were continued. The objective was to simulate furnace conditions at the Greenidge boiler No. 6 owned and operated by NYSEG and to improve themore » process performance. The tests were conducted in EER's Boiler Simulator Facility (BSF). During the reporting period, measurements of CO and ammonia emissions were conducted for reburn + SNCR conditions, as well as tests on the effect of sodium on NO{sub x} control efficiency. Exhaust levels of CO remained below 100 ppm in all tests. Prospective process conditions for the full-scale facility have been identified that can provide over 80% NO{sub x} reduction while maintaining ammonia slip below 4 ppm. Addition of sodium resulted in NO{sub x} control improvement of about 7-10 percentage points. The objective of modeling work was to further understand the influence of the mixing process on gas reburning and to identify factors that can increase the effectiveness of NO reduction. Modeling results demonstrated that the main features of gas reburning could be described using a detailed chemical mechanism with one-dimensional representation of mixing.« less
  • This project is designed to develop a family of novel NO{sub x} control technologies, called Second Generation Advanced Reburning which has the potential to achieve 90+ NO{sub x} control in coal fired boilers at a significantly lower cost than Selective Catalytic Reduction. The sixth reporting period in Phase II (January 1-March 31, 1999) included experimental activities and combined chemistry-mixing modeling on advanced gas reburning. The goal of combustion tests was to continue the work on identifying prospective promoters for the advanced reburning process. Tests were conducted in Controlled Temperature Tower (CTT) and Boiler Simulator Facility (BSF). Tests showed that somemore » promoters significantly affect the reburning process when co-injected with NH{sub 3} . The promoters injected into reburning zone without NH{sub 3} in the amount 30 ppm do not significantly affect the reburning process. The modeling effort was focused on the description of Na effect on CO emissions in advanced reburning. Increase in CO concentration in flue gas upon Na injection results from inhibition of CO oxidation by Na species in the burnout zone.« less
  • This project is designed to develop a family of novel NO{sub x} control technologies, called Second Generation Advanced Reburning which has the potential to achieve 90+ NO{sub x} control in coal fired boilers at a significantly lower cost than Selective Catalytic Reduction. The eighth reporting period in Phase II (July 1--September 26, 1999) included combined chemistry-mixing modeling on advanced gas reburning and experimental activities in support of modeling. Modeling efforts focused on description of AR-Lean--combination of basic reburning and co-injection of N-agent with overfire air. Modeling suggests that efficiency of AR-Lean strongly depends on the amount of the reburning fuel,more » temperature of flue gas at the point of OFA/N-agent injection, and evaporation time of N-agent. The model describes the most important features of AR-Lean and can be used for AR-Lean optimization.« less
  • This project is designed to develop a family of novel NO{sub x} control technologies, called Second Generation Advanced Reburning which has the potential to achieve 90+ NO{sub x} control in coal fired boilers at a significantly lower cost than Selective Catalytic Reduction. The seventh reporting period in Phase II (April 1-June 30, 1999) included experimental activities and combined chemistry-mixing modeling on advanced gas reburning. The goal of combustion tests was to determine the efficiency of advanced reburning using coal as the reburning fuel. Tests were conducted in Boiler Simulator Facility (BSF). Several coals were tested. The modeling effort was focusedmore » on the description of N-agent injection along with overfire air. Modeling identified process parameters that can be used to optimize the AR-Lean process.« less