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Title: FY05 LDRD Final Report Molecular Engineering of Electrodialysis Membranes 03-ERD-060

Technical Report ·
DOI:https://doi.org/10.2172/898481· OSTI ID:898481

Using a combination of modeling and experimental work we have developed a new method for purifying water that uses less energy than conventional methods and that can be made selective for removing targeted contaminants. The method uses nanoporous membranes that are permselective for anion or cation transfer. Ion selectivity results from double layer overlap inside the pores such that they dominantly contain ions opposite in charge to the surface charge of the membrane. Membrane charge can be adjusted through functionalization. Experiments confirm membrane permselectivity and overall energy use less than that for conventional electrodialysis. The nanoporous membranes are used in a conventional electrodialysis configuration and can be incorporated in existing electrodialysis systems without modification. The technology merits further development and testing in real systems, and could result in a significant reduction in water treatment costs.

Research Organization:
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
W-7405-ENG-48
OSTI ID:
898481
Report Number(s):
UCRL-TR-219452; TRN: US200708%%113
Country of Publication:
United States
Language:
English