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CO2 Capture by Absorption with Potassium Carbonate

Technical Report ·
DOI:https://doi.org/10.2172/895539· OSTI ID:895539
The objective of this work is to improve the process for CO{sub 2} capture by alkanolamine absorption/stripping by developing an alternative solvent, aqueous K{sub 2}CO{sub 3} promoted by piperazine. Ethylenediamine was detected in a degraded solution of MEA/PZ solution, suggesting that piperazine is subject to oxidation. Stripper modeling has demonstrated that vacuum strippers will be more energy efficient if constructed short and fat rather than tall and skinny. The matrix stripper has been identified as a configuration that will significantly reduce energy use. Extensive measurements of CO{sub 2} solubility in 7 m MEA at 40 and 60 C have confirmed the work by Jou and Mather. Corrosion of carbon steel without inhibitors increases from 19 to 181 mpy in lean solutions of 6.2 m MEA/PZ as piperazine increases from 0 to 3.1 m.
Research Organization:
University Of Texas At Austin
Sponsoring Organization:
USDOE
DOE Contract Number:
FC26-02NT41440
OSTI ID:
895539
Country of Publication:
United States
Language:
English

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