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Characterizing Recombination in CdTe Solar Cells with Time-Resolved Photoluminescence: Preprint

Conference ·

Time-resolved photoluminescence (TRPL) computer simulations demonstrate that under certain experimental conditions it is possible to assess recombination in CdTe solar cells in spite of the junction. This is supported by experimental findings that open-circuit voltage (Voc) is dependent on lifetime in a manner consistent with device theory. Measurements on inverted structures show that the CdCl2 treatment significantly reduces recombination in the CdTe layer without S diffusion. However, S diffusion is required for lifetimes comparable to those observed in high-efficiency solar cells. The results indicate that substrate solar cells can be fabricated with recombination lifetimes similar to superstrate cells.

Research Organization:
National Renewable Energy Laboratory (NREL), Golden, CO.
Sponsoring Organization:
USDOE
DOE Contract Number:
AC36-99GO10337
OSTI ID:
891542
Report Number(s):
NREL/CP-520-39926
Country of Publication:
United States
Language:
English